Damn, this surprises me. Look at some stats, people:
# Youngest goaltender to win 300 regular-season games: Martin Brodeur (age 29 yrs., 7 mos.)
# Youngest goaltender to win 400 regular-season games: Martin Brodeur (age 31 yrs., 10 mos.)
# Youngest goaltender to win 500 regular-season games: Martin Brodeur (age 35 yrs., 6 mos.)
# Youngest goaltender to win 600 regular-season games: Martin Brodeur (age 37 yrs., 11 mos.)
http://en.wikipedia.org/wiki/List_of_NHL_records_(individual)#Goaltending
Brodeur is amazing. He's like Roy without the princess attitude (or the distracting head jerks).
Knowing all that, it's still a hard choice. I think, overall, I'd pick Brodeur during his peak (which is long past, he needs to retire).